The Chemical EducatorISSN: 1430-4171 (electronic version) Abstract Volume 6
Issue 3 (2001) pp 161-163 Volume Nonadditivity of Liquid Mixtures: Modifications to Classical DemonstrationsVladimir M. Petruševski* and Metodija Z. Najdoski Institut za hemija, PMF, Univerzitet “Sv. Kiril i Metodij”, Arhimedova
5, PO Box 162, 1001 Skopje, Macedonia Published online: 13 April 2001 Abstract. Departures
from Raoult’s law are often found in liquid mixtures resulting in volume
nonadditivity. Modifications are proposed for experiments demonstrating
volume contraction of water/ethanol and volume expansion of ethyl acetate/carbon
disulfide liquid mixtures. A layer of paraffin oil or water is used to
prevent mixing of the liquids at an earlier stage then desired. A demonstration
of volume expansion in a CS2/ethyl acetate system is proposed
as well. The modifications significantly improve the ease of the demonstrations,
which can be made even more impressive by coloring the liquids. A reaction
vessel of simple construction is offered for a more vivid demonstration
of the phenomenon.
Key Words: Laboratories and Demonstrations; physical chemistry; general chemistry; Raoult; volume contraction; volume expansion; intermolecular forces (*) Corresponding author. (E-mail: vladop@iunona.pmf.ukim.edu.mk) Article in PDF format (133 KB) HTML format Supporting Materials: Movies and Photographs of demo (7.54 MB ZIP file) 10.1007/s00897000477b Photo 1 (239 KB) JPEG file Issue date: June 1, 2001 |