The Chemical Educator
ISSN: 1430-4171 (electronic version)
Abstract Volume 17
(2012) pp 053-056
Hammett Correlations of Benzhydrylium Cations
William H. Parsons, Louisa Hong, J. Hodge Markgraf‡, and Sarah L. Goh*,†
Department of Chemistry, Williams College, Williamstown,
01267-2692 USA, email@example.com
Published: 23 March 2012
Abstract. This laboratory experiment investigates linear free energy relationships between Hammett s+ parameters and the 1H-NMR chemical shifts of substituted benzhydrol reagents. The significance of resonance and field effects on proton shielding can be determined by relating chemical shift data to various forms of Hammett equations. Benzhydrylium cations can be studied as well by 13C-NMR spectroscopy.
Key Words: Laboratories and Demonstrations; physical organic chemistry; linear free energy relationships; Hammett correlations
(*) Corresponding author. (E-mail: firstname.lastname@example.org)
Supporting Materials:A student handout and synthesis and characterization data of benzhydrols derivatives that are not commercially available are provided in the supporting materials. 1H-NMR spectra and 13C-NMR data for 2 are also include (872 KB).