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The Chemical Educator

ISSN: 1430-4171 (electronic version)

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Abstract Volume 23 (2018) pp 1-10

Conductometric Versus Potentiometric Autotitrimetry

John C. O’C. Young

Department of Chemistry, Saint Mary’s University, Halifax, Nova Scotia, Canada B3H 3C3, john.young@smu.ca
Received May 4, 2017. Accepted December 5, 2017.

Published: 4 January 2018

Abstract. Sensor response lag is a significant problem in autotitrimetry and, for a variety of analyte-titrant combinations, more accurate and more rapidly responsive conductometric monitoring of the progress of their titrations is shown to be preferable to conventional potentiometric sensing of analyte concentrations with a pH electrode.

Key Words: Laboratories and Demonstrations; analitic chemistry; autotitrimetry; drop counting; conductivity and pH measurement; sensor response lag

(*) Corresponding author. (E-mail: john.young@smu.ca)

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